During the time, High Sur is actually a beat outpost and household from Henry Miller and the screenwriter Dennis Murphy, every one of which Thompson recognized. During this time, he composed his first journal feature in to the Rogue regarding the artisan and you will bohemian people of Highest Sur and you will labored on The newest Rum Record. He been able to publish you to definitely small-facts, «Burial during the Ocean,» that can starred in Rogue.
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This indicates the lattice planes (0.21 nm) coming from diamond are based on the newest graphite (002) flat because of the lattice distortion. For town 4 (FT4), diamond lattice fringes (0.21 nm) become the main lattice with a near disappearance away from graphite (002) lattice fringes, proving you to definitely graphite totally transits to help you diamond. Through the 150 to help you 210 s, the change inside the Raman spectra is similar to that of 30 to 90 s, confirming that periodic alter noticed in the exterior morphology originates regarding the alternative look of VGs and you will NCD. FESEM pictures to have trials broadening playing with (A) 0 s, (B) 29 s, (C) 60 s, (D) 90 s, (E) 120 s, (F) 150 s, (G) 180 s, and you may (H) 210 s inside the next gains procedure in the step 1,800 W.
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It demonstrates that from the H, O, and you will Ta cutting-edge surroundings of the CVD environment, diamond is created by stage conversion process of graphite. This also will bring an angle to understand the organization mechanism away from product having sp2 and you may sp3 digital web site settings. X-ray photoelectron spectroscopy (XPS) (Fig. 4A and Si Appendix, Fig. S7) suggests noticeable Ta and you can O attribute intake peaks, where outdoors atoms is bonded with carbon. Furthermore, HAADF and energy dispersive spectrometry (EDS) mapping photos (Fig. 4B) reveal atomically distribute Ta atoms. This gives all of us motivation to decide whether or not Ta atoms enjoy a key character from the stage changeover.
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